Cmc.log is full of Errors: Error creating RRD for pnp_multiple... but this RRD exists

The possible problem is that you have a system with “mixed” RRDs at the moment.
Can you have a look at your “~/var/pnp4nagios/perfdata/” folder and check how many data is there left after the convert?
If you check this for one if the entries from the log you should find an RRD file but no corresponding XML i think.